Safety Data Sheet - Bizol

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Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 1 of 8

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Bizol Radiator Repair+ r71 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Heat transfer fluids 1.3. Details of the supplier of the safety data sheet Company name: BIZOL BITA Trading GmbH Street: Martin-Buber-Str. 12 Place: D-14163 Berlin

Telephone: e-mail: Internet:

Telefax: +49 (30) 804 869-2860

+49 (30) 804 869-0 [email protected] www.bizol.com

Germany: +49 (30) 804 869-0 (08.00-17.00, Mo-Fr) In England and Wales: NHS Direct: 0845 4647 or 111 In Scotland: NHS 24 08454 24 24 24 In Republic of Ireland: 01 809 2166

1.4. Emergency telephone number:

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Specific target organ toxicity - repeated exposure: STOT RE 2 Hazard Statements: May cause damage to organs through prolonged or repeated exposure. 2.2. Label elements Regulation (EC) No. 1272/2008 Hazard components for labelling ethanediol Signal word:

Warning

Pictograms:

Hazard statements H373

May cause damage to organs through prolonged or repeated exposure.

Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P260 Do not breathe vapour/aerosol. P314 Get medical advice/attention if you feel unwell. P501 Dispose of waste according to applicable legislation. 2.3. Other hazards Results of PBT and vPvB assessment: not applicable.

SECTION 3: Composition/information on ingredients 3.2. Mixtures

Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 2 of 8

Hazardous components CAS No

Chemical name EC No

Quantity Index No

REACH No

Classification according to Regulation (EC) No. 1272/2008 [CLP] 107-21-1

ethanediol 203-473-3

10 - < 20 % 603-027-00-1

01-2119456816-28

Acute Tox. 4, STOT RE 2; H302 H373 12179-04-3

disodium tetraborate pentahydrate 215-540-4

0,1 - < 1 % 005-011-02-9

Repr. 1B; H360FD 7632-00-0

sodium nitrite 231-555-9

0,1 - < 1 % 007-010-00-4

01-2119471836-27

Ox. Sol. 3, Acute Tox. 3, Eye Irrit. 2, Aquatic Acute 1; H272 H301 H319 H400

Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures General information When in doubt or if symptoms are observed, get medical advice. If unconscious place in recovery position and seek medical advice. Remove contaminated, saturated clothing immediately. After inhalation Remove casualty to fresh air and keep warm and at rest. After contact with skin After contact with skin, wash immediately with plenty of water and soap. After contact with eyes After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then consult an ophthalmologist immediately. After ingestion If swallowed, rinse mouth with water (only if the person is conscious). Let water be drunken in little sips (dilution effect). Call a physician immediately. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed When in doubt or if symptoms are observed, get medical advice. 4.3. Indication of any immediate medical attention and special treatment needed No information available.

SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media alcohol resistant foam, Extinguishing powder, Carbon dioxide (CO2). Unsuitable extinguishing media High power water jet. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products: Carbon monoxide Carbon dioxide (CO2). Do not inhale explosion and combustion gases. 5.3. Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Do not allow to enter into soil/subsoil.

SECTION 6: Accidental release measures Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 3 of 8

6.1. Personal precautions, protective equipment and emergency procedures See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Clean contaminated articles and floor according to the environmental legislation. 6.3. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. 6.4. Reference to other sections See protective measures under point 7 and 8.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Use personal protection equipment. Do not eat, drink or smoke when using this product. Provide fresh air. Handle and open container with care. Conditions to avoid: generation/formation of aerosols. Advice on protection against fire and explosion No special measures are necessary. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Protect against: Frost. Keep away from heat. Protect against direct sunlight. Keep container tightly closed in a cool, well-ventilated place. 7.3. Specific end use(s)

Observe technical data sheet.

SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No

Substance

107-21-1

Ethane-1,2-diol, vapour

ppm

mg/m³

20 40

fibres/ml

Category

Origin

52

TWA (8 h)

WEL

104

STEL (15 min)

WEL

DNEL/DMEL values CAS No

Substance

DNEL type

Exposure route

Effect

Value

Worker DNEL, long-term

inhalation

local

35 mg/m³

Consumer DNEL, long-term

inhalation

local

7 mg/m³

Consumer DNEL, long-term

dermal

systemic

53 mg/kg bw/day

Worker DNEL, long-term

dermal

systemic

106 mg/kg bw/day

107-21-1

ethanediol

PNEC values CAS No

Substance

Environmental compartment 107-21-1

Value

ethanediol

Freshwater

10 mg/l

Soil

1,53 mg/kg

Freshwater sediment

20,9 mg/kg

Marine water

1 mg/l

Micro-organisms in sewage treatment plants (STP)

199,5 mg/l

Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 4 of 8

8.2. Exposure controls Appropriate engineering controls See chapter 7. No additional measures necessary. Protective and hygiene measures When using do not eat, drink, smoke, sniff. Eye/face protection Eye glasses with side protection. Hand protection Wear suitable gloves. Recommended glove articles: DIN EN 374. Suitable material: NBR (Nitrile rubber). Breakthrough time (maximum wearing time): > 480 min (Thickness of the glove material: 0.4 mm). Breakthrough times and swelling properties of the material must be taken into consideration. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Barrier creams can help protecting exposed skin areas. In no case should they be used after contact. Skin protection Protective clothing. Respiratory protection

With correct and proper use, and under normal conditions, breathing protection is not required. When splashes or fine mist form, a permitted breathing apparatus suitable for these purposes must be used. Suitable respiratory protection apparatus: Filtering Half-face mask (DIN EN 149), e.g. FFA P / FFP3. Environmental exposure controls Do not allow to enter into surface water or drains.

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties

Physical state: Colour: Odour:

liquid light brown characteristic Test method

pH-Value:

not applicable

Changes in the physical state Melting point:

not determined

Initial boiling point and boiling range: Pour point:

not determined not applicable

Flash point:

not applicable

Lower explosion limits: Upper explosion limits:

not determined not determined

Ignition temperature:

not determined

Decomposition temperature:

No information available.

Vapour pressure:

not determined

Density:

1,035 g/cm³

Water solubility:

miscible

Partition coefficient:

not determined

Viscosity / dynamic:

not determined

Viscosity / kinematic:

not determined

Flow time:

not determined

Vapour density:

not determined

Evaporation rate:

not determined

9.2. Other information

No information available. Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 5 of 8

SECTION 10: Stability and reactivity 10.1. Reactivity No information available. 10.2. Chemical stability

No information available. 10.3. Possibility of hazardous reactions

No hazardous reaction when handled and stored according to provisions. 10.4. Conditions to avoid Heat. 10.5. Incompatible materials No information available. 10.6. Hazardous decomposition products No information available.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. CAS No

Chemical name Exposure route

107-21-1

12179-04-3

7632-00-0

Dose

Species

Source

ethanediol oral

LD50

1600 mg/kg

Practical experience/human evidence

dermal

LD50

3500 mg/kg

Mouse

oral

LD50 mg/kg

3200 - 3400

Rat

dermal

LD50

> 2000 mg/kg

Rabbit

inhalative (4 h) aerosol

LC50

> 2 mg/l

oral

LD50

180 mg/kg

Rat

inhalative (4 h) aerosol

LC50

5,5 mg/l

Rat

disodium tetraborate pentahydrate

sodium nitrite GESTIS

Irritation and corrosivity Based on available data, the classification criteria are not met. Sensitising effects Based on available data, the classification criteria are not met. Carcinogenic/mutagenic/toxic effects for reproduction Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. ( (ethanediol)) Aspiration hazard Based on available data, the classification criteria are not met. Practical experience Other observations Keeping to the general worker's protection rules and the industrial hygienics, there is no risk in handling this product through the personnel. Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 6 of 8

SECTION 12: Ecological information 12.1. Toxicity There are no data available on the mixture itself. CAS No

Chemical name Aquatic toxicity

107-21-1

7632-00-0

[h] | [d] Species

Dose

Source

ethanediol Acute fish toxicity

LC50

72860 mg/l

96 h Pimephales promelas (fathead minnow)

Acute algae toxicity

ErC50 mg/l

6500-13000

96 h Selenastrum capricornutum

Acute crustacea toxicity

EC50

> 100 mg/l

48 h Daphnia magna (Big water flea)

Fish toxicity

NOEC

15380 mg/l

7 d Pimephales promelas (fathead minnow)

Crustacea toxicity

NOEC

8590 mg/l

7 d Ceriodaphnia Dubia

LC50 mg/l

0,56 - 1,78

96 h Onchorhynchus mykiss

sodium nitrite Acute fish toxicity Acute algae toxicity

ErC50

>100 mg/l

72 h Desmodesmus subspicatus

Acute crustacea toxicity

EC50 mg/l

12,5 - 100

48 h Daphnia magna

OECD 201

12.2. Persistence and degradability

There are no data available on the mixture itself. CAS No

Chemical name Method

Value

d

90-100

10

Source

Evaluation 107-21-1

ethanediol Biodegradation OECD 301A/ ISO 7827/ EEC 92/69/V, C.4-A

12.3. Bioaccumulative potential

There are no data available on the mixture itself. Partition coefficient n-octanol/water Log Pow

CAS No

Chemical name

107-21-1

ethanediol

-1,36

7632-00-0

sodium nitrite

-3,7

12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment No data available 12.6. Other adverse effects No data available

SECTION 13: Disposal considerations 13.1. Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste disposal according to EC directives 75/442/EEC and 91/689/EEC in the corresponding versions, covering waste and dangerous waste. Waste disposal number of waste from residues/unused products

Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015 070701

Page 7 of 8

WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fine chemicals and chemical products not otherwise specified; aqueous washing liquids and mother liquors Classified as hazardous waste.

Contaminated packaging Non-contaminated packages may be recycled. Consult the appropriate local waste disposal expert about waste disposal.

SECTION 14: Transport information Land transport (ADR/RID) 14.1. UN number:

No dangerous good in sense of this transport regulation.

14.2. UN proper shipping name:

No dangerous good in sense of this transport regulation.

14.3. Transport hazard class(es):

No dangerous good in sense of this transport regulation.

14.4. Packing group:

No dangerous good in sense of this transport regulation.

Marine transport (IMDG) 14.1. UN number:

No dangerous good in sense of this transport regulation.

14.2. UN proper shipping name:

No dangerous good in sense of this transport regulation.

14.3. Transport hazard class(es):

No dangerous good in sense of this transport regulation.

14.4. Packing group: Marine pollutant:

No dangerous good in sense of this transport regulation. NO

Air transport (ICAO-TI/IATA-DGR) 14.1. UN number:

No dangerous good in sense of this transport regulation.

14.2. UN proper shipping name:

No dangerous good in sense of this transport regulation.

14.3. Transport hazard class(es):

No dangerous good in sense of this transport regulation.

14.4. Packing group:

No dangerous good in sense of this transport regulation.

14.5. Environmental hazards

ENVIRONMENTALLY HAZARDOUS:

no

14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code No data available

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information

Authorisations (REACH, annex XIV): Substances of very high concern, SVHC (REACH, article 59): disodium tetraborate pentahydrate Restrictions on use (REACH, annex XVII): Entry 30: disodium tetraborate pentahydrate 2010/75/EU (VOC):

0%

National regulatory information

Water contaminating class (D):

1 - slightly water contaminating

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information Abbreviations and acronyms ADR: Accord européen relatif au transport international des marchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement concernant le transport international ferroviaire des marchandises dangereuses (Regulations concerning the International Carriage of Dangerous Goods by Rail) Revision No: 1,0

GB - EN

Print date: 21.02.2017

Safety Data Sheet according to Regulation (EC) No 1907/2006

Bizol Radiator Repair+ r71 Revision date: 28.01.2015

Page 8 of 8

IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organization CAS: Chemical Abstracts Service (a division of the American Chemical Society) DNEL/DMEL: Derived No-Effect Level / Derived Minimal Effect Level PNEC: Predicted No Effect Concentration WEL (UK): Workplace Exposure Limits TWA (EC): Time-Weighted Average STEL (EC): Short Term Exposure Limit ATE: Acute Toxicity Estimate LD50: Lethal Dose, 50% (median lethal dose) LC50: Lethal Concentration, 50% (median lethal concentration) EC50: half maximal Effective Concentration ErC50: EC50 in terms of reduction of growth rate VwVwS: Verwaltungsvorschrift wassergefährdende Stoffe Relevant H and EUH statements (number and full text) H272 May intensify fire; oxidiser. H301 Toxic if swallowed. H302 Harmful if swallowed. H319 Causes serious eye irritation. H360FD May damage fertility. May damage the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)

Revision No: 1,0

GB - EN

Print date: 21.02.2017

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Safety Data Sheet - Bizol

Safety Data Sheet according to Regulation (EC) No 1907/2006 Bizol Radiator Repair+ r71 Revision date: 28.01.2015 Page 1 of 8 SECTION 1: Identificat...

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