Material Safety Data Sheet

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Latest revision date: 11/24/2013 Version: 1.1

United States

Material Safety Data Sheet 24 h. EMERGENCY TELEPHONE NUMBER CHEMTREC (U.S.) 1-800-424-9300 CHEMTREC (International) 1-703-527-3887 Non-Emergency Calls 1-937-644-0011

The Ortho Group P.O. Box 190 Marysville, Ohio 43040 United States

ORTHO WEED B GON MAX PLUS CRABGRASS CONTROL 1. Product and company identification : :

320000000300 239-2689

Physical state

:

liquid [liquid]

Color Signal word OSHA/HCS status

: : :

Amber. CAUTION! This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. Wash throughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco.

: : : : :

Toxic by inhalation. No known significant effects or critical hazards. Very toxic in contact with skin. No known significant effects or critical hazards. None known.

MSDS # EPA Registration Number:

2. Hazards identification

Emergency Overview

Potential acute health effects Inhalation Ingestion Skin Eyes Target organs

Potential chronic health effects : See section 11 for more information. Over-exposure signs/symptoms No specific data. Inhalation : No specific data. Ingestion : No specific data. Skin : No specific data. Eyes : None known. Medical conditions aggravated : by over-exposure See toxicological information (Section 11)

3. Composition/information on ingredients

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

Page:2/7

There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

4. First aid measures Eye contact

:

Skin contact

:

Inhalation

:

Ingestion

:

Notes to physician

:

Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Never give anything by mouth to an unconscious person. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

5. Fire-fighting measures :

No specific fire or explosion hazard.

: :

Use an extinguishing agent suitable for the surrounding fire. None known.

Special exposure hazards

:

Hazardous thermal decomposition products Special protective equipment for fire-fighters

:

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. No specific data.

Flammability of the product Extinguishing media Suitable Not suitable

:

Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental release measures Personal precautions

:

Environmental precautions

:

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment (see Section 8). To protect the environment, do not allow pesticide to enter or run-off into storm drains, drainage ditches gutters or surface waters

Methods for cleaning up Small spill

Version:

:

Report version.Re port version

Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

Page:3/7

:

Vacuum or sweep up material and place in container for disposal. Never place down drain.

Handling

:

Storage

:

Avoid inhalation or contact with skin, eyes or clothing. Avoid container breakage. Do not contaminate water sources when disposing of equipment washwater or rinsate. Keep out of lakes, stream or ponds. Keep out of reach of children. Store in original container in a cool, dry, well-ventilated area inaccessible to children and pets. Do not contaminate food or feedstuffs.

Large spill

7. Handling and storage

8. Exposure controls/personal protection Occupational exposure limits No exposure standard allocated. Consult local authorities for acceptable exposure limits. Recommended monitoring procedures

:

Engineering measures

:

Hygiene measures

:

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use adequate ventilation to keep the airborne concentrations below the recommended exposure standard. Wash thoroughly with soap and water after handling. Remove and launder contaminated clothing before reuse.

Personal protection Respiratory

:

Hands Eyes Skin Environmental exposure controls

: : : :

No special respiratory protection required. If ventilation is inadequate to keep the airborne concentrations below the recommended exposure standard wear appropriate respiration protection. Chemical-resistant gloves. Protective eyewear. Wear long-sleeved shirt, long pants, shoes with socks. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

9. Physical and chemical properties Physical state Flash point Burning time Auto-ignition temperature Flammable limits Density Color Odor pH Boiling/condensation point

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Report version.Re port version

: : : : : : : : : :

liquid [liquid] Not Applicable Not Applicable Not Applicable Not Applicable 8.34 lb/gal Amber. Not Applicable 8.7 Not Applicable

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

Page:4/7

Melting/freezing point Relative density Vapor pressure Vapor density Volatility Odor threshold Evaporation rate Viscosity Solubility Solubility in water

: : : : : : : : : :

Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

: : : :

The product is stable. No specific data. No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur.

10. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions

:

11. Toxicological information Acute toxicity Product/ingredient name Product Product Product

Result LD50 Oral LC50 Inhalation LD50 Dermal

Species Rat Rat Rabbit

Dose > 5,000 mg/kg 2.03 mg/l 5,000 mg/kg

Conclusion/Summary

Very low toxicity to humans or animals.

Irritation/Corrosion Skin Eyes Respiratory

Slight May cause eye irritation. May cause respiratory irritation

Sensitizer Conclusion/Summary

Skin Respiratory

Not sensitizing Not sensitizing - based on the individual components.

Chronic toxicity Conclusion/Summary

No known significant effects or critical hazards.

Carcinogenicity Conclusion/Summary

No known significant effects or critical hazards.

Mutagenicity Conclusion/Summary

No known significant effects or critical hazards.

Teratogenicity Product/ingredient name Conclusion/Summary

Version:

Report version.Re port version

Result

Exposure 4h -

Species

Dose

Exposure

No known significant effects or critical hazards.

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

Page:5/7

Reproductive toxicity Conclusion/Summary

No known significant effects or critical hazards.

12.Ecological information :

This pesticide is toxic to fish and aquatic invertebrates

:

No known significant effects or critical hazards.

Conclusion/Summary

:

No known significant effects or critical hazards.

Partition coefficient: noctanol/water Other adverse effects

:

No known significant effects or critical hazards.

:

No known significant effects or critical hazards.

Ecotoxicity Aquatic ecotoxicity Conclusion/Summary Persistence/degradability

13. Disposal considerations Waste disposal

Disposal should be in accordance with applicable regional, national and local laws and regulations.

14.Transport information Regulatory information UN no. DOT IATA (C) IATA (P) IMDG TDG PG* : Packing group

Proper shipping name Not Regulated Not Regulated

Class

PG*

Note

Not Regulated Not Regulated

15.Regulatory information United States U.S. Federal regulations

Version:

Report version.Re port version

:

SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: The following components are listed: Potassium hydroxide (K(OH)) Clean Air Act (CAA) 112 accidental release prevention: No products

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

Page:6/7

were found. Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

:

All components are listed or exempted.

State regulations Massachusetts

:

None of the components are listed.

New York

:

None of the components are listed.

New Jersey

:

None of the components are listed.

Pennsylvania

:

None of the components are listed.

California Prop. 65

:

Not listed.

:

At least one component is not listed.

United States inventory (TSCA 8b)

International regulations Canada inventory International lists

: Australia inventory (AICS): At least one component is not listed. Japan inventory: At least one component is not listed. China inventory (IECSC): At least one component is not listed. Korea inventory: At least one component is not listed. New Zealand Inventory of Chemicals (NZIoC): At least one component is not listed. Philippines inventory (PICCS): At least one component is not listed.

16.Other information Hazardous Material Information System (U.S.A.) : 1 Health 0 Flammability 0 Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

Page:7/7

National Fire Protection Association (U.S.A.): Flammability 0 Health

1

0

Instability/Reactivity

Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of printing Date of issue Version

: : :

Print date Validity date***. Report version.Report version

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

10/07/2011

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Material Safety Data Sheet

Page:1/7 Latest revision date: 11/24/2013 Version: 1.1 United States Material Safety Data Sheet 24 h. EMERGENCY TELEPHONE NUMBER CHEMTREC (U.S.) 1-...

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