Material Safety Data Sheet

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Latest revision date: 05/25/2015 Version: 1.2

United States

Material Safety Data Sheet The Ortho Group P.O. Box 190 Marysville, Ohio 43040 United States

ORTHO WEED B GON WEED KILLER FOR LAWNS

Section 1. Identification GHS product identifier Product type SDS # EPA Registration Number:

ORTHO WEED B GON WEED KILLER FOR LAWNS Pesticide 320000002486 239-2682

: : : :

Relevant identified uses of the substance or mixture and uses advised against Use only in accordance with label directions.

Section 2. Hazards identification This product is regulated by the Environmental Protection Agency (EPA) for label precautionary text see Section 15. OSHA/HCS status

:

While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product.

Classification of the substance or mixture

:

Not classified.

Signal word

:

None

Hazard statements

:

No known significant effects or critical hazards.

General

:

Prevention Response Storage

: : :

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Not applicable. Not applicable. Not applicable.

GHS label elements

Precautionary statements

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

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Disposal Supplemental label elements Hazards not otherwise classified

: : :

Not applicable. None known. None known.

Section 3. Composition/information on ingredients Substance/mixture Chemical name Other means of identification

: : :

Mixture

Not available. Not available.

Ingredient name

%

CAS number

dimethylammonium 2,4-dichlorophenoxyacetate

0.1 - 0.3

2008-39-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation. Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures Description of necessary first aid measures Eye contact

:

Inhalation

:

Skin contact

:

Ingestion

:

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Inhalation Skin contact Ingestion

: : : :

No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

: : : :

No specific data. No specific data. No specific data. No specific data.

Over-exposure signs/symptoms Eye contact Inhalation Skin contact Ingestion

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:3/10

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician

:

Specific treatments

:

Protection of first-aiders

:

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. No specific treatment.

No action shall be taken involving any personal risk or without suitable training.

See toxicological information (Section 11)

Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

: :

Use an extinguishing agent suitable for the surrounding fire. None known.

Specific hazards arising from the chemical Hazardous thermal decomposition products

:

In a fire or if heated, a pressure increase will occur and the container may burst. No specific data.

Special protective actions for firefighters

:

Special protective equipment for fire-fighters

:

:

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel

:

For emergency responders

:

Environmental precautions

:

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:4/10

Spill

:

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene

: :

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

:

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits

None. Appropriate engineering controls

:

Environmental exposure controls

:

Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures Hygiene measures

Version:

Report version.Re port version

:

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:5/10

Eye/face protection

:

of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Protective eyewear is not required, but may be used in situations were contact is expected.

Skin protection Hand protection

:

Body protection Other skin protection

: :

Respiratory protection

:

Protective gloves are not required, but may be used in situations were significant contact is expected. No special protective clothing is required. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties Appearance Physical state Color

: :

liquid Amber.

Odor Odor threshold pH

: : :

Not available. Not available. 8

Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density

: : : : : :

Not available. Not available. Not available. Not available. Not available. Lower: Not available.

: : :

1.00

Solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature

: :

Not available. Not available.

: :

Not available. Not available.

Version:

Report version.Re port version

Upper: Not available.

Not available. Not available.

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:6/10

Viscosity

:

Dynamic: Not available. Kinematic: Not available.

Section 10. Stability and reactivity Reactivity

:

Chemical stability Possibility of hazardous reactions

: :

Conditions to avoid Incompatible materials Hazardous decomposition products

: : :

No specific test data related to reactivity available for this product or its ingredients. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. No specific data. No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name

Conclusion/Summary

Result

Species

Dose

Exposure

LD50 Oral LC50 Inhalation LD50 Dermal

Rat Rat Rat

> 5,000 mg/kg > 5 mg/l > 5,000 mg/kg

-

:

No known significant effects or critical hazards.

Irritation/Corrosion Product/ingredient name

Conclusion/Summary Skin Eyes Respiratory

Result Eyes Redness of the conjunctivae Skin Erythema/Es char

: : :

Species Rabbit

Score 1.0

Rabbit

1.0

Exposure

Observation -

-

Mildly irritating Mildly irritating Non-irritating

Sensitization Product/ingredient name

Version:

Report version.Re port version

Route of exposure

Date of issue/Date of revision:

Species

Validity date***.

Result

Date of previous issue:

11/24/2013

Page:7/10

Skin Conclusion/Summary Skin Respiratory

Guinea pig

Not sensitizing

: :

Not sensitizing Not sensitizing

:

No known significant effects or critical hazards.

:

No known significant effects or critical hazards.

:

No known significant effects or critical hazards.

:

No known significant effects or critical hazards.

Mutagenicity Conclusion/Summary Carcinogenicity Conclusion/Summary Reproductive toxicity Conclusion/Summary Teratogenicity Conclusion/Summary

Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Velcro Closure :

Not available.

Conclusion/Summary

:

No known significant effects or critical hazards.

General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects

: : : : : :

No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

Information on the likely routes of exposure

Potential chronic health effects

Section 12. Ecological information Toxicity

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:8/10

Conclusion/Summary

:

Not available.

:

No known significant effects or critical hazards.

:

Not available.

:

No known significant effects or critical hazards.

Persistence and degradability Conclusion/Summary

Mobility in soil Soil/water partition coefficient (KOC) Other adverse effects

Section 13. Disposal considerations Disposal methods

:

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information Regulatory information UN no. DOT IATA (C) IATA (P) IMDG TDG PG* : Packing group

Proper shipping name Not Regulated Not Regulated

Version:

PG*

Note

Not Regulated Not Regulated

Special precautions for user

Report version.Re port version

Class

:

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:9/10

Section 15. Regulatory information Precautionary statements Signal word Emergency Overview

: :

U.S. Federal regulations

CAUTION! Keep out of reach of children. :

United States inventory (TSCA 8b): Not determined.

: : : : : : : : : :

At least one component is not listed.

State regulations California Prop. 65 Not available. International lists National inventory Australia Canada China Europe Japan Malaysia New Zealand Philippines Republic of Korea Taiwan

At least one component is not listed. At least one component is not listed. At least one component is not listed. At least one component is not listed. Not determined. At least one component is not listed. At least one component is not listed. At least one component is not listed. Not determined.

Section 16. Other information National Fire Protection Association (U.S.A.): Flammability

0 Health

0

0

Instability/Reactivity

Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

Page:10/10

hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue/Date of revision Version

: :

Validity date***. Report version.Report version

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Version:

Report version.Re port version

Date of issue/Date of revision:

Validity date***.

Date of previous issue:

11/24/2013

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Material Safety Data Sheet

Page:1/10 Latest revision date: 05/25/2015 Version: 1.2 United States Material Safety Data Sheet The Ortho Group P.O. Box 190 Marysville, Ohio 4304...

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