Material Safety Data Sheet

Loading...

NICKEL SULFAMATE SOLUTION

MSDS

Material Safety Data Sheet

1. Product and Company Identification 1.1

Product name

:

Nickel sulfamate solution

1.2

Application of the substance

:

Not Classified

1.3

Manufacturer/Supplier

1.3.1

Manufacturer -

Company

: MK Chem & Tech Co., Ltd

-

Address

: 778-7 wonsi-dong, Danwon-gu

Ansan city, Gyunggido ,

Korea

1.3.2

-

Telephone

:

82-31-491-7979

-

Fax

:

82-31-492-7171

Supplier -

Company

: MK Chem & Tech Co., Ltd

-

Address

: 778-7 wonsi-dong, Danwon-gu

Ansan city, Gyunggido ,

Korea -

Telephone

:

82-31-491-7979

-

Fax

:

82-31-492-7171

2. Hazards Identification 2.1 Hazard class -

Physical hazards

Not Classified

-

Health hazards

Carcinogenicity, Inhalation: Category 1A Germ cell mutagenicity :Category 2 Reproductive toxicity: Category 1B Specific target organ toxicity - repeated exposure : Category 1 Respiratory sensitization: Category 1 Skin sensitization: Category 1 Acute aquatic toxicity: Category 1 Chronic aquatic toxicity: Category 1

-

Environmental hazard

Not Classified

-

Symbol

-

Signal word

: Danger

-

Hazard statement

H317 Causes serious eye damage. -1-

NICKEL SULFAMATE SOLUTION

MSDS H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer H360 May damage the unborn child. H372 Cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement

-

1)

Preventions

P201 Obtain special instructions before use. P261. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection.

2)

Response

P308+P313 If exposed or concerned: Get medical advice/attention.

3)

Storage

P405 Store locked up.

4)

Disposal

P501 Dispose of contents/container to local/regional/national/international regulations.

NFPA rating

-

Health = 1 Flammability = 0 Instability = 0

3. Composition/information on ingredients Component

CAS #

Amount W/W(%)

Nickel sulfamate

13770-89-3

65

D. I. Water

7732-18-5

35

4. First-aid Measures 4.1

Eye Contact

- Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist.

4.2

Skin contact

- Wash skin with plenty of water. consult a physician.

4.3

Inhalation

- Move person to fresh air; if effects occur, consult a physician. -2-

NICKEL SULFAMATE SOLUTION 4.4

Ingestion

MSDS - Do not induce vomiting. Give one cup (8 ounces or 240 ml) of water or milk if available and transport to a medical facility. Do not give anything by mouth to an unconscious person.

4.5

Note to Physician

- Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest endotracheal/esophageal control if lavage is done. If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

5. Fire Fighting Measures 5.1

Extinguishing Media

- To extinguish combustible residues of this product use water fog, carbondioxide, dry chemical or foam.

5.2

Unusual Fire and Explosion Hazards

- This material will not burn until the water has evaporated. Residue can burn.

5.3

Special Protective Equipment for firefighters

- Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

6. Accidental Release Measures

6.1

Personal Precautions

- Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures.

6.2

Environmental Precautions

- Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

6.3

Step to be taken if Material is Released or Spilled

- Contain spilled material if possible. Absorb with materials such as: Dirt. Sand. Collect in suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional information. -3-

NICKEL SULFAMATE SOLUTION

MSDS

7. Handling and Storage 7.1

Handling

- Do not swallow. Avoid contact with eyes. Avoid contact with skin and clothing.Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.

7.2

Storage

- Store in accordance with good manufacturing practices. Do not store in: Zinc. Aluminum. Carbon steel. Copper. Copper alloys. Additional storage and handling information on this product may be obtained by calling your Dow sales or customer service contact.

8. Exposure Controls/Personal Protection 8.1

Exposure Limits

-NICKEL SULFAMATE: Regulation of KOR - [TWA 0.1ppm]

8.2

Engineering Controls

- Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

8.3

Personal Protection -

Respiratory Protection

- Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. In misty atmospheres, use an approved particulate respirator. The following should be effective types of airpurifying respirators: Organic vapor cartridge with a particulate pre-filter. Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating..

-

Eye Protection

- Use chemical goggles.

-

Hand Protection

- Use gloves chemically resistant to this material when -4-

NICKEL SULFAMATE SOLUTION

MSDS prolonged or frequently repeated contact could occur. If hands are cut or scratched, use gloves chemically resistant to this material even for brief exposures. Examples of preferred glove barrier materials include: Polyethylene. Neoprene. Natural rubber ("latex"). Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Ethyl vinyl alcohol laminate ("EVAL"). Avoid gloves made of: Polyvinyl alcohol ("PVA"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

-

Skin Protection

- When prolonged or frequently repeated contact could occur, use protective clothing chemically resistant to this material. Selection of specific items such as faceshield, boots, apron, or full-body suit will depend on the task. If hands are cut or scratched, use gloves chemically resistant to this material even for brief exposures.

9. Physical and Chemical Properties 9.1

Physical state

: Green liquid

9.2

Odor

: Not Classified

9.3

pH

: 3.0~5.0(20℃)

9.4

Flash Point

: Not Classified

9.5

Autoignition Temperature

: Not Classified

9.6

Vapor Pressure

: Not Classified

9.7

Boiling Point

: Not Classified

9.8

Vapor density

: Not Classified

9.9

Specific Gravity

: 1.560~1.580(20℃)

9.10

Freezing/Melting Point

: Not Classified

9.11

Solubility in Water

: Not Classified

9.12

Decomposition Temperature

: Not Classified

9.13

Kinematic Viscosity

: Not Classified

-5-

NICKEL SULFAMATE SOLUTION

MSDS

10. Stability and Reactivity 10.1

Chemical Stability

- Thermally stable at typical use temperatures.

10.2

Conditions to Avoid

- Active ingredient decomposes at elevated temperatures.

10.3

Incompatibilities with Other Materials

- Avoid contact with: Oxidizers. Flammable hydrogen may be generated from contact with metals such as: Aluminum.

10.4

Hazardous Decomposition Products

- Sulfate gas may occur.

11. Toxicological Information 11.1

Acute Toxicity -

Oral

- LD50

923 mg/kg Rat

-

Dermal

- Not Classified

-

Inhalation

- Not Classified

11.2

Skin corrosion/irritation

- Not Classified

11.3

Serious eye damage/eye irritation

- Not Classified

11.4

Respiratory or skin sensitisation

- May cause allergic respiratory and skin reactions - Not Classified

11.5

Carcinogenicity

- IARC: 1 - Group 1: Carcinogenic to humans

11.6

Germ cell mutagenicity

- Not Classified

11.7

Reproductive toxicity

- Not Classified.

11.8

Specific target organ toxicity

- Not Classified

(single exposure) 11.9

Specific target organ toxicity

- Not Classified

(repeated exposure) 11.10

Aspiration hazard

- Not Classified

12. Ecological Information 12.1

Hazardous to the aquatic environment -

Fish

- LC50

> 100 ㎎/ℓ

-

Crustacea

- LC50

> 100 ㎎/ℓ

-

Algae

- EC50

> 100 ㎎/ℓ

12.2

Persistence & Resolvability

- Not Classified

12.3

Bioaccumulation

- Not Classified

12.4

Soil mobility

- Not Classified

12.5

Other harmful influence

- Very toxic to aquatic life.

13. Disposal Considerations -6-

NICKEL SULFAMATE SOLUTION

MSDS

DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator

14. Transport Information 14.1

UN No.

- Not Classified

14.2

Technical Name

- Not Classified

14.3

Hazard Class

- Not Classified

14.4

Packing Group

- Not Classified

14.5

Environmental Hazard

- Not Classified

15. Regulatory Information 15.1

occupation safety and health acts (KOR)

- Harmful Agent Required to work environment monitoring - Harmful Agent Required to manage

15.2

Toxic chemical control act (KOR)

- Not Classified

15.3

Safety control of dangerous substances act

- Not Classified

(KOR) 15.4

Wastes Control act (KOR)

- Controlled wastes

15.5

Other regulations

- Not Classified

16. Other Information 16.1

Reference

Ministry of Government Legislation of Korea Korea Occupational Safety & Health Agency IMDG CODE Manual

16.2

Created

JUNE.28.2012

16.3

Last Updated

JUNE.29.2012

-7-

Loading...

Material Safety Data Sheet

NICKEL SULFAMATE SOLUTION MSDS Material Safety Data Sheet 1. Product and Company Identification 1.1 Product name : Nickel sulfamate solution 1...

128KB Sizes 4 Downloads 0 Views

Recommend Documents

Material Safety Data Sheet
May 25, 2015 - Date of previous issue: 11/24/2013. United States. Material Safety Data Sheet. The Ortho Group. P.O. Box

Material Safety Data Sheet
Nov 24, 2013 - United States. Material Safety Data Sheet. The Ortho Group. P.O. Box 190. Marysville, Ohio 43040. United

MATERIAL SAFETY DATA SHEET
ORTHO® Weed-B-Gon® MAX® Concentrate Page i of 5. MATERIAL SAFETY DATA SHEET. DATE PREPARED:DB/I ”2004. MSDS Nu:04l0

MATERIAL SAFETY DATA SHEET
Product and Company Identification. Material name. 5000-Sc Cleaning Solution. Revision date. 03-08-2011. Version #. 01.

Material Safety Data Sheet
May 13, 2017 - Evaporation Rate: No data available. Flammability (solid, gas):. No data available. Upper/lower limit on

material safety data sheet - GRANTT
GRANTT AW 68 GOLD - Hydraulic/22/05/15/Rev-01. Page 8 of 13. 4. LANGKAH-LANGKAH PERTOLONGAN CEMAS. 4.1 Pengenalan langka

material safety data sheet - Matheson
Jan 24, 1989 - point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition ... TERT-BUTYL CHLOR

Material Safety Data Sheet - Dentalcompare.com
Jul 11, 2011 - ... 3M makes no representations as to its completeness or accuracy. In addition, information obtained fro

Armacell WWW 10. material safety data sheet
C, Extinguishing Media: Water. D, Special Fire Fighting Procedures: Protect fire fighters from toxic products of combust

material safety data sheet - Science Stuff
May 28, 2013 - MATERIAL SAFETY DATA SHEET. Buffer Solution, pH 9. SECTION 3 MIXTURE COMPONENTS. SECTION 1 . Product and

weiches Polster Möbel PVC KUNSTLEDER Rindsleder Optik Breite 140cm Sitzbezug | Watch movie | Ruched Plus Size Mesh Panel Swimsuit